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| Tom Cruise | .... | Ethan Hunt |
| Dougray Scott | .... | Sean Ambrose |
| Thandie Newton | .... | Nyah Nordoff-Hall |
| Ving Rhames | .... | Luther Stickell |
| Richard Roxburgh | .... | Hugh Stamp |
| John Polson | .... | Billy Baird |
| Brendan Gleeson | .... | John C. McCloy |
| Rade Serbedzija | .... | Dr. Nekhorvich |
| William Mapother | .... | Wallis |
| Dominic Purcell | .... | Ulrich |
| Matthew Wilkinson | .... | Michael |
| Nicholas Bell | .... | McCloy's Accountant |
| Cristina Brogers | .... | Flamenco Dancer #4 |
| Kee Chan | .... | McCloy's Chemist |
| Kim Fleming | .... | Larrabee |
| Anthony Hopkins | .... | Mission Cmdr. Swanbeck |
